Paper Type |
: |
Research Paper |
Title |
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Room Temperature Synthesis of Zinc Zno and Azo Thin Films by
Successive Ionic Layer Adsorption and Reaction Method and Its
Structural and Optical Characterization |
Country |
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Nigeria |
Authors |
: |
Ayodeji Oladiran Awodugba, Ayooye Abigael Olawoyin |
 |
: |
10.9790/4861-0163641  |
Abstract:ZnO and Al-doped ZnO (AZO) thin films were grown by Successive Ionic Layer Adsorption an
Reaction (SILAR) method on a glass substrate from sodium zincate solution. Doping was achieved with
controlled introduction of aluminum chloride. The technique involved multiple dipping of the substrate in an
aqueous solution of sodium zincate kept at room temperature and a hot water bath kept at 95oC in which ZnO
and AZO thin films were synthesized at 0.125M and 0.25M of sodium zincate (Na2ZnO2) where 100 and 200
dippings were performed for each. The thickness of the layers were determined using Metler PB303 digital
balance and a Radicon 10 mini- diffractometer (XRD) for the structural characterization while optical
characterization was achieved with the use of a Jenway 6405 UV-Vis Spectrophotometer. The results revealed
(002) peaks for ZnO thin films and (112) peaks for AZO thin films. Also the transmittances of the ZnO films
were higher than those of AZO while AZO films have higher absorbance than those of ZnO films. The energy
band gap of both ZnO and AZO were both found to be between 3.71eV and 3.80eV, the values which are slightly
higher than most reported values in literature.
Keywords - Absorbance, AZO, Energy bandgap, SILAR, Thin Films, XRD, ZnO
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