ABSTRACT: The kinetics of crystallization of different crystalline phases of Fe73.5Ag1Nb3Si13.5B9 has been studied by differential thermal analysis (DTA). DTA diagrams of amorphous ribbons were taken in nitrogen atmosphere with continuous heating rate of 10 -50°C/min in step of 10°C. The primary exothermic peaks temperature for α-Fe (Si) was found 6030C and the secondary exothermic peak temperature for Fe2B phase was found 7680C at the same heating rate 200C/min.The kinetics of glass formation and crystallization in composition is studied as affected to differential thermal analysis. Thermal analysis experiment and from the obtained data the activation energy is found 4.37eVand 4.45eV respectively. For primary crystallization product,α-Fe(si) phase of the ribbon and nanocrystalline state was evaluated by XRD. The alloy has been annealed in a controlled way in the temperature range of 4500 C to 8000C for 30.....
Keyword: DTA, XRD, VSM, Activation energy,Lattice Parameter and Curie Temperature
[1]. Mohammad MahmuduzzamanTawhid, Sujit Kumar Shil, Mohammad TahmidShihab, ShibendraShekherSikder, Mohammad
Abdul gofur, "The Crystallization Kinetics, Structural and Magnetic Properties of Amorphous Ribbon as Affected by Annealing" ;
American Journal of nanoreasearch and Application.Vol6,No.3, ,pp.60-66, 2018.
[2]. KaziHanium Maria, Mondal S. P, ShamimaChowdhury, Sikder S. S, Hakim M. A. and Saha D. K; "Effect of annealing temperature
on the soft magnetic properties of Fe75.5Cu1Nb1Si13.5B9 Amorphous alloys", Journal Emerging Trends sciences (JETEAS), 2 (i), 102
- 108, 2011
[3]. Kulik T., Hernando A. and Vasquez M.; "Correlation between structure and the magnetic properties of amorphous and
nanocrystalline Fe73.5Cu1Nb3Si22.5-XB9 [X = Cu, Ag & Au] alloys", J. Magn. Magn.Mater., 133, 310, 1994.
[4]. Jing Zhi, Kai-Yuan He, Li-Zhi Cheng and Yu-Jan Fu; "Influence of the elements Si/B on the structure and magnetic properties of
nanocrystalline (Fe,Cu,Nb)73.5SiXB22-X [X = Cu, Ag & Au] alloys"; J. Magn. Magn.Matter 9, 153 315, 1996.
[5]. Kane S. N, Sarabhai S., Gupta A., Varga L. K, Kulit T.; "Effect of quenching rate on crystallization in Fe73.5Cu1Nb3Si22.5-XB9
alloys"; J. Magn. Magn.Mater., 215-216, 372, 2000.