ABSTRACT: Pure and Zn, PVP and Ag doped tin oxide nanoparticles were prepared by microwave assisted chemical co-precipitation method. The influence of zinc, PVP and Ag nanoparticles in tin oxide is obtained by X-ray Diffraction pattern and Electrical conductivity studies. The Ag and Zn ions replaced the tin ions in tin oxide lattice sites. Therefore, no zinc and silver peaks are observed in XRD. There is no impurity peak observed in XRD. The X-ray diffraction pattern reveals the tetragonal rutile structure of tin oxide nanoparticles. Increasing the doping concentration of zinc in tin oxide decrease the crystalline size. The band gap of pure and zinc, PVP and Ag doped tin oxide nanoparticles are calculated from Diffuse reflectance spectroscopy.The conductivity studies of the doped samples is increased due to the Ag nanoparticles.
Keywords: UV-Visible absorption spectroscopy, SnO2 nanoparticles, Conductivity, Bandgap.
[1]. Aparna G, Anubhav S, Santanu C, Titash M, Influence of Nanofillers on Adhesion Properties of Polymeric Composites. Acs omega 2022; 7:3844−3859.
[2]. Dorel F, Polyblend Nanocomposites, Journal of Macromolecular Science, Part A: Pure and Applied Chemistry,2022 ;52:8, 648-658.
[3]. Mei G, Li Z, Yi Z, Qin Z, Yanying W, Li W, Yubao L, Investigation on the Interpenetrating Polymer Networks (IPNs) of Polyvinyl Alcohol and Poly (N-vinyl pyrrolidone) Hydrogel and Its In Vitro Bioassessment. Journal of Applied Polymer Science, 2012; 125, 2799–2806.
[4]. Rabia J, Muhammad Z, Sania N, Samson O. A, Noorul A, Qiang A, Role of capping agents in the application of nanoparticles in biomedicine and environmental remediation: recent trends and future prospects,2020;18:172.
[5]. Kallum M. K, Stefanos M, Lakshminarayana P, Sara E, Polyvinylpyrrolidone (PVP) in nanoparticle synthesis Dalton Transactions. 2015; 1-22.