ABSTRACT:Perovskites are materials with a wide range of possible uses, including humidity sensors, photocatalysts, transparent conductive oxides, and capacitors. A perovskite semi-conductor material with a broad band gap is strontium stannate (SrSnO3). To create SrSnO3, a number of synthesis techniques are frequently employed, such as hydrothermal, sol-gel, and solid-state reaction (SSR). High temperature calcination is necessary for the SSR process. However, the hydrothermal and sol-gel processes just require a lower calcination temperature to produce perovskite materials. Prior to calcination, a surfactant was added to a solution of Sr(NO3)2 and SnCl2 in water in order to perform the sol-gel procedures. SrSnO3 was formed by the hydrothermal process using the autoclave procedure before calcination. Determining the morphological and optical characteristics of SrSnO3 produced by sol-gel, hydrothermal, and SSR processes was the aim of this investigation. Using Kubelka-Munk relations, the band gap was determined to be 4.05 eV for hydrothermal, 5.50 eV for sol-gel, and 3.95 eV for SSR. For SrSnO3, sol-gel techniques revealed the largest band gap. Optical studies demonstrated that a perovskite produced using the various techniques has a distinct band gap.
[1]. Abrari M, Ahmadi M, Ghanaatshoar M, Moazami HR, Davarani SSH (2019) Fabrication of dye-sensitized solar cells based on SnO2/ZnO composite nanostructures: a new facile method using dual anodic dissolution. J Alloys Compd 784:1036–1046 [2]. de Sousa Filho, I. A.; Arana, L. R.; Doungmo, G.; Grisolia, C. K.; Terrashke, H.; Weber, I. T. SrSnO3/g-C3N4 and sunlight: Photocatalytic activity and toxicity of degradation byproducts. J. Environ. Chem. Eng. 2020, 8, 103633. [3]. Ecija, A., Vidal, K., Larrañaga, A., Ortega-san-martín, L., Arriortua, M. I., Euskal, V. and Ehu, U. (2012). Synthetic methods for perovskite materials – structure and morphology. Advances in Crystallization Processes, 19: 485–505. [4]. James, K., Aravind, A. and Jayaraj, M. (2013). Structural, optical and magnetic properties of Fe-doped barium stannate thin films grown by PLD. Applied Surface Science, 282: 121–125. [5]. Kumar, A., Quamara, J., Dillip, G., Joo, S. and Kumar, J. (2015). Fe(III) induced structural, optical, and dielectric behavior of cetyltrimethyl ammonium bromide stabilized strontium stannate nanoparticles synthesized by a facile wet chemistry route. RSC Advance, 5(22): 17202–17209.